Molecular structure of 8-hydroxy-1-methylquinolinium iodide hydrate in crystal and solution
| dc.contributor.author | Barczyński, Piotr | |
| dc.contributor.author | Komasa, Anna | |
| dc.contributor.author | Ratajczak-Sitarz, Małgorzata | |
| dc.contributor.author | Katrusiak, Andrzej | |
| dc.contributor.author | Brzezinski, Bogumil | |
| dc.date.accessioned | 2018-03-22T14:11:30Z | |
| dc.date.available | 2018-03-22T14:11:30Z | |
| dc.date.issued | 2006-06-29 | |
| dc.description.abstract | 8-Hydroxy-1-methylquinolinium iodide monohydrate [(C10H10NO)I-+(-) H2O] has been studied by X-ray diffraction, FF-IR, H-1 and C-13 NMR spectroscopy. In the crystalline state, the iodide anion is hydrogen-bonded to the water molecule, which in turn is hydrogen bonded to the 8-OH group of the 8-hydroxyquinolinium ring, forming of a symmetric dimer. In acetonitrile and DMSO-d(6) the hydrate assumes a new structure due to almost complete dissociation of the water molecule from the complex structure. In acetonitrile the 8-OH group is hydrogen-bonded to the iodide anion, whereas in DMSO-d(6) it forms the hydrogen bond with the solvent molecules. This 8-OH... O(DMSO-d(6)) hydrogen bond is the strongest within the structure of the hydrate. | pl |
| dc.identifier.citation | Journal of Molecular Structure 791 (2006) 106–110 | pl |
| dc.identifier.issn | 0022-2860 | |
| dc.identifier.uri | http://hdl.handle.net/10593/22316 | |
| dc.language.iso | eng | pl |
| dc.rights | info:eu-repo/semantics/openAccess | pl |
| dc.subject | 8-hydroxy-1-methylquinolinium cation | pl |
| dc.subject | intermolecular hydrogen bonds | pl |
| dc.subject | halides | pl |
| dc.subject | X-ray structure | pl |
| dc.subject | hydrates | pl |
| dc.subject | FT-IR, H-1 NMR, C-13 NMR | pl |
| dc.title | Molecular structure of 8-hydroxy-1-methylquinolinium iodide hydrate in crystal and solution | pl |
| dc.type | Artykuł | pl |