Electrifying synthesis of organosilicon compounds – from electrosynthesis to electrocatalysis

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2023-02-02

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The Royal Society of Chemistry

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Abstract

Occasionally, a synthetic strategy is developed that seems to be a game changer. Not long ago, mechanochemistry or ionic liquids were intensively explored to afford organosilicon compounds. These and other approaches still offer benefits and influence the development of this field. Electrochemistry is currently a new synthetic strategy. Despite its long history, electrosynthesis or electrocatalysis have not become routine procedures in the synthesis of organosilicons. One may justifiably ask why. Accessibility and reproducibility are one of the challenges of electrochemical approaches. However, recent developments in the field of electrified organic synthesis have provided new insights and allowed electrochemistry to become an approachable tool. In this perspective article, several notable contributions to the electrochemical synthesis of organosilicon compounds are highlighted.

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This is the Accepted Version of the following article: Krzysztof Kuciński, Electrifying synthesis of organosilicon compounds – from electrosynthesis to electrocatalysis, Inorganic Chemistry Frontiers, 2023, 10, 1382-1394, DOI: 10.1039/D2QI02713E, which has been published at https://pubs.rsc.org/en/content/articlelanding/2023/qi/d2qi02713e#!divAbstract In accordance with the RSC's publishing policy and the fact that the above-mentioned article has already been published via open access, the author of the manuscript has the right to publish the Author Accepted Manuscript version in an open repository.

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This work was supported by a National Science Centre Grant UMO-2021/43/D/ST4/00132.

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Inorganic Chemistry Frontiers

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Uniwersytet im. Adama Mickiewicza w Poznaniu
Biblioteka Uniwersytetu im. Adama Mickiewicza w Poznaniu
Ministerstwo Nauki i Szkolnictwa Wyższego