Please use this identifier to cite or link to this item: https://hdl.handle.net/10593/14621
Title: Geochemistry of rare earth elements in the Baba Ali magnetite skarn deposit, western Iran – a key to determine conditions of mineralisation
Authors: Zamanian, Hassan
Radmard, Kaikosrov
Keywords: Almoughlagh
Ce/Ce* ratio
Eu/Eu* ratio
La/Y ratio
Issue Date: Apr-2016
Publisher: Instytut Geologii UAM
Citation: Geologos, 2016, 22, 1, pp.33-47.
Abstract: The Baba Ali skarn deposit, situated 39 km to the northwest of Hamadan (Iran), is the result of a syenitic pluton that intruded and metamorphosed the diorite host rock. Rare earth element (REE) values in the quartz syenite and diorite range between 35.4 and 560 ppm. Although the distribution pattern of REEs is more and less flat and smooth, light REEs (LREEs) in general show higher concentrations than heavy REEs (HREEs) in different lithounits. The skarn zone reveals the highest REE-enriched pattern, while the ore zone shows the maximum depletion pattern. A comparison of the concentration variations of LREEs (La–Nd), middle REEs (MREEs; Sm–Ho) and HREEs (Er–Lu) of the ore zone samples to the other zones elucidates two important points for the distribution of REEs: 1) the distribution patterns of LREEs and MREEs show a distinct depletion in the ore zone while representing a great enrichment in the skarn facies neighbouring the ore body border and decreasing towards the altered diorite host rock; 2) HREEs show the same pattern, but in the exoskarn do not reveal any distinct increase as observed for LREEs and MREEs. The ratio of La/Y in the Baba Ali skarn ranges from 0.37 to 2.89. The ore zone has the highest La/Y ratio. In this regard the skarn zones exhibit two distinctive portions: 1) one that has La/Y >1 beingadjacent to the ore body and; 2) another one with La/Y < 1 neighbouring altered diorite. Accordingly, the Baba Ali profile, from the quartz syenite to the middle part of the exoskarn, demonstrates chiefly alkaline conditions of formation, with a gradual change to acidic towards the altered diorite host rocks. Utilising three parameters, Ce/Ce*, Eu/Eu* and (Pr/Yb)n, in different minerals implies that the hydrothermal fluids responsible for epidote and garnet were mostly of magmatic origin and for magnetite, actinolite and phlogopite these were of magmatic origin with low REE concentration or meteoric water involved.
URI: http://hdl.handle.net/10593/14621
DOI: 10.1515/logos-2016-0003
ISBN: ISBN 978-83-232187-4-6
ISSN: ISSN 1426-8981
Appears in Collections:Geologos, 2016, 22, 1

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